Age determination of highly enriched uranium: separation and analysis of 231Pa.

نویسندگان

  • A Morgenstern
  • C Apostolidis
  • K Mayer
چکیده

An analytical procedure has been developed for the age determination of highly enriched uranium samples exploiting the mother/daughter pair 235U/231Pa. Protactinium is separated from bulk uranium through highly selective sorption to silica gel and is subsequently quantified using alpha-spectrometry. The method has been validated using uranium standard reference materials of known ages. It affords decontamination factors exceeding 2.5 x 10(7), overall recoveries in the range of 80-85%, and a combined uncertainty below 5%.

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عنوان ژورنال:
  • Analytical chemistry

دوره 74 21  شماره 

صفحات  -

تاریخ انتشار 2002